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Application Note: Rapid, Ultra sensitive Detection of Atmospheric Organonitrates

Organonitrates play a pivotal role in atmospheric chemistry: they regulate the NOₓ budget, drive secondary organic aerosol formation, and act as reservoirs for long-range nitrogen transport. Measuring these compounds at ultra-trace levels in humid, chemically complex air remains a significant analytical challenge.

Karsa’s MION2 Orbitrap chemical ionization mass spectrometer (CIMS) addresses this challenge by combining ultra-high mass resolution with flexible, real-time ionization strategies. Capable of resolving isobaric and isotopically substituted compounds at sub-pptv levels, the system enables continuous, in situ detection of organonitrates under both laboratory and ambient conditions. Recent demonstrations show robust, humidity-independent performance, capturing oxidation products of α-pinene in controlled experiments and revealing diurnal cycles of organonitrates in Helsinki’s urban atmosphere.

With its sensitivity, selectivity, and adaptability, the MION2 Orbitrap CIMS provides scientists with a reliable platform for investigating oxidation chemistry in the atmosphere—from mechanistic studies to real-world field campaigns.

Time‑series of nitrate‑cluster ions. The individual traces are color‑coded by the total number of oxygen atoms, fewer oxygens in cooler colors, more oxygens in warmer ones.

Download the application note:

MION Orbitrap Organonitrates Application Note 250820
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